Synthesis, structural characterization and magnetism of the solid solution: Copper nickel pyrophosphate
Identifieur interne : 001024 ( Main/Exploration ); précédent : 001023; suivant : 001025Synthesis, structural characterization and magnetism of the solid solution: Copper nickel pyrophosphate
Auteurs : A. Handizi [Maroc] ; A. Boukhari [Maroc] ; E. M. Holt [États-Unis] ; J. Aride [Maroc] ; S. Flandrois [France]Source :
- Materials Research Bulletin [ 0025-5408 ] ; 1993.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
The solid solution, Cu2−xNixP2O7 (0≤x≤2), has been synthesized and characterized by X-ray diffraction on powder. A study of the crystal chemistry of this system has revealed the existence of a phase, Cu2−xNixP2O7 (0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu2P2O7 and β-Ni2P2O7. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni2+ for Cu2+ in the solid state lattice of Cu2P2O7.
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DOI: 10.1016/0025-5408(93)90171-9
Affiliations:
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A study of the crystal chemistry of this system has revealed the existence of a phase, Cu2−xNixP2O7 (0.04≤x≤1.75), isomorphous with the high temperature forms: β-Cu2P2O7 and β-Ni2P2O7. The magnetism of this phase has been measured at x=0.25, 0.5, 1.0, 1.5 and 1.75 between 5.2 and 300 K. Antiferromagnetic interactions between ions weaken with the substitution of Ni2+ for Cu2+ in the solid state lattice of Cu2P2O7.</div></front></TEI><affiliations><list><country><li>France</li><li>Maroc</li><li>États-Unis</li></country><region><li>Aquitaine</li><li>Nouvelle-Aquitaine</li><li>Rabat-Salé-Kénitra</li></region><settlement><li>Rabat</li></settlement></list><tree><country name="Maroc"><region name="Rabat-Salé-Kénitra"><name sortKey="Handizi, A" sort="Handizi, A" uniqKey="Handizi A" first="A." last="Handizi">A. Handizi</name></region><name sortKey="Aride, J" sort="Aride, J" uniqKey="Aride J" first="J." last="Aride">J. 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